FR 132 then AZ 75 at Barcelona
Berlin → Barcelona → Rome
Timetable, Barcelona time
13:20FR 132 from Berlin at the gate
06:20AZ 75 to Rome leaves the gate
17 h apart on the timetable, overnight
AZ 75 leaves 17 h after FR 132 arrives on the timetable: more than half a day, so not a connection we count.