FR 132 then FR 3180 at Barcelona
Berlin → Barcelona → Rome
Timetable, Barcelona time
13:20FR 132 from Berlin at the gate
07:55FR 3180 to Rome leaves the gate
18 h 35 apart on the timetable, overnight
FR 3180 leaves 18 h 35 after FR 132 arrives on the timetable: more than half a day, so not a connection we count.