FR 132 then IB 5462 at Barcelona
Berlin → Barcelona → Bordeaux
Timetable, Barcelona time
17:30FR 132 from Berlin at the gate
16:40IB 5462 to Bordeaux leaves the gate
23 h 10 apart on the timetable, overnight
IB 5462 leaves 23 h 10 after FR 132 arrives on the timetable: more than half a day, so not a connection we count.