FR 132 then W4 6728 at Barcelona
Berlin → Barcelona → Venezia
Timetable, Barcelona time
22:35FR 132 from Berlin at the gate
22:30W4 6728 to Venezia leaves the gate
23 h 55 apart on the timetable, overnight
W4 6728 leaves 23 h 55 after FR 132 arrives on the timetable: more than half a day, so not a connection we count.