FR 1526 then FR 133 at Barcelona
Valletta → Barcelona → Berlin
Timetable, Barcelona time
15:55FR 1526 from Valletta at the gate
11:50FR 133 to Berlin leaves the gate
19 h 55 apart on the timetable, overnight
FR 133 leaves 19 h 55 after FR 1526 arrives on the timetable: more than half a day, so not a connection we count.