FR 270 then LS 804 at Barcelona
Milan → Barcelona → Manchester
Timetable, Barcelona time
16:45FR 270 from Milan at the gate
12:00LS 804 to Manchester leaves the gate
19 h 15 apart on the timetable, overnight
LS 804 leaves 19 h 15 after FR 270 arrives on the timetable: more than half a day, so not a connection we count.