FR 2835 then FR 867 at Barcelona
Brussels Charleroi → Barcelona → Venezia
Timetable, Barcelona time
08:05FR 2835 from Brussels Charleroi at the gate
22:50FR 867 to Venezia leaves the gate
14 h 45 apart on the timetable
FR 867 leaves 14 h 45 after FR 2835 arrives on the timetable: more than half a day, so not a connection we count.