FR 3181 then LL 5002 at Barcelona
Rome → Barcelona → Amsterdam
Timetable, Barcelona time
15:05FR 3181 from Rome at the gate
11:35LL 5002 to Amsterdam leaves the gate
20 h 30 apart on the timetable, overnight
LL 5002 leaves 20 h 30 after FR 3181 arrives on the timetable: more than half a day, so not a connection we count.