FR 4596 then QR 3530 at Barcelona
Porto → Barcelona → Palma de Mallorca
Timetable, Barcelona time
22:15FR 4596 from Porto at the gate
19:25QR 3530 to Palma de Mallorca leaves the gate
21 h 10 apart on the timetable, overnight
QR 3530 leaves 21 h 10 after FR 4596 arrives on the timetable: more than half a day, so not a connection we count.