FR 5271 then FR 133 at Barcelona
Manchester → Barcelona → Berlin
Timetable, Barcelona time
21:55FR 5271 from Manchester at the gate
11:50FR 133 to Berlin leaves the gate
13 h 55 apart on the timetable, overnight
FR 133 leaves 13 h 55 after FR 5271 arrives on the timetable: more than half a day, so not a connection we count.