FR 5271 then FR 3166 at Barcelona
Manchester → Barcelona → Palermo
Timetable, Barcelona time
16:20FR 5271 from Manchester at the gate
08:30FR 3166 to Palermo leaves the gate
16 h 10 apart on the timetable, overnight
FR 3166 leaves 16 h 10 after FR 5271 arrives on the timetable: more than half a day, so not a connection we count.