FR 5271 then FR 6330 at Barcelona
Manchester → Barcelona → Sofia
Timetable, Barcelona time
21:55FR 5271 from Manchester at the gate
17:15FR 6330 to Sofia leaves the gate
19 h 20 apart on the timetable, overnight
FR 6330 leaves 19 h 20 after FR 5271 arrives on the timetable: more than half a day, so not a connection we count.