FR 574 then VY 4221 at Barcelona
Bologna → Barcelona → Berlin
Timetable, Barcelona time
21:10FR 574 from Bologna at the gate
13:05VY 4221 to Berlin leaves the gate
15 h 55 apart on the timetable, overnight
VY 4221 leaves 15 h 55 after FR 574 arrives on the timetable: more than half a day, so not a connection we count.