FR 574 then W9 5362 at Barcelona
Bologna → Barcelona → London Luton
Timetable, Barcelona time
11:20FR 574 from Bologna at the gate
09:50W9 5362 to London Luton leaves the gate
22 h 30 apart on the timetable, overnight
W9 5362 leaves 22 h 30 after FR 574 arrives on the timetable: more than half a day, so not a connection we count.