FR 59 then LA 5746 at Barcelona
Napoli → Barcelona → Amsterdam
Timetable, Barcelona time
12:50FR 59 from Napoli at the gate
11:35LA 5746 to Amsterdam leaves the gate
22 h 45 apart on the timetable, overnight
LA 5746 leaves 22 h 45 after FR 59 arrives on the timetable: more than half a day, so not a connection we count.