FR 59 then LS 804 at Barcelona
Napoli → Barcelona → Manchester
Timetable, Barcelona time
12:50FR 59 from Napoli at the gate
12:25LS 804 to Manchester leaves the gate
23 h 35 apart on the timetable, overnight
LS 804 leaves 23 h 35 after FR 59 arrives on the timetable: more than half a day, so not a connection we count.