FR 6596 then EW 7525 at Barcelona
Manchester → Barcelona → Hamburg
Timetable, Barcelona time
23:40FR 6596 from Manchester at the gate
19:00EW 7525 to Hamburg leaves the gate
19 h 20 apart on the timetable, overnight
EW 7525 leaves 19 h 20 after FR 6596 arrives on the timetable: more than half a day, so not a connection we count.