FR 6596 then EW 9445 at Barcelona
Manchester → Barcelona → Düsseldorf
Timetable, Barcelona time
21:05FR 6596 from Manchester at the gate
16:20EW 9445 to Düsseldorf leaves the gate
19 h 15 apart on the timetable, overnight
EW 9445 leaves 19 h 15 after FR 6596 arrives on the timetable: more than half a day, so not a connection we count.