FR 6596 then FR 149 at Barcelona
Manchester → Barcelona → Berlin
Timetable, Barcelona time
23:40FR 6596 from Manchester at the gate
14:20FR 149 to Berlin leaves the gate
14 h 40 apart on the timetable, overnight
FR 149 leaves 14 h 40 after FR 6596 arrives on the timetable: more than half a day, so not a connection we count.