FR 6596 then FR 6330 at Barcelona
Manchester → Barcelona → Sofia
Timetable, Barcelona time
23:40FR 6596 from Manchester at the gate
17:15FR 6330 to Sofia leaves the gate
17 h 35 apart on the timetable, overnight
FR 6330 leaves 17 h 35 after FR 6596 arrives on the timetable: more than half a day, so not a connection we count.