FR 6596 then IB 416 at Barcelona
Manchester → Barcelona → Madrid
Timetable, Barcelona time
23:40FR 6596 from Manchester at the gate
17:00IB 416 to Madrid leaves the gatealso IB 416S, LL 3016, VY 5068, QR 6587, BA 7083, CZ 7325, AA 8732
17 h 20 apart on the timetable, overnight
IB 416 leaves 17 h 20 after FR 6596 arrives on the timetable: more than half a day, so not a connection we count.