FR 6596 then LL 5026 at Barcelona
Manchester → Barcelona → Brussels
Timetable, Barcelona time
23:40FR 6596 from Manchester at the gate
19:00LL 5026 to Brussels leaves the gate
19 h 20 apart on the timetable, overnight
LL 5026 leaves 19 h 20 after FR 6596 arrives on the timetable: more than half a day, so not a connection we count.