FR 6596 then LL 5122 at Barcelona
Manchester → Barcelona → Munich
Timetable, Barcelona time
23:40FR 6596 from Manchester at the gate
14:00LL 5122 to Munich leaves the gate
14 h 20 apart on the timetable, overnight
LL 5122 leaves 14 h 20 after FR 6596 arrives on the timetable: more than half a day, so not a connection we count.