FR 6596 then LL 5468 at Barcelona
Manchester → Barcelona → Lyon
Timetable, Barcelona time
23:40FR 6596 from Manchester at the gate
16:30LL 5468 to Lyon leaves the gate
16 h 50 apart on the timetable, overnight
LL 5468 leaves 16 h 50 after FR 6596 arrives on the timetable: more than half a day, so not a connection we count.