FR 6596 then W4 6020 at Barcelona
Manchester → Barcelona → Rome
Timetable, Barcelona time
23:40FR 6596 from Manchester at the gate
22:00W4 6020 to Rome leaves the gate
22 h 20 apart on the timetable, overnight
W4 6020 leaves 22 h 20 after FR 6596 arrives on the timetable: more than half a day, so not a connection we count.