FR 6921 then FR 133 at Barcelona
Dublin → Barcelona → Berlin
Timetable, Barcelona time
12:00FR 6921 from Dublin at the gate
11:50FR 133 to Berlin leaves the gate
23 h 50 apart on the timetable, overnight
FR 133 leaves 23 h 50 after FR 6921 arrives on the timetable: more than half a day, so not a connection we count.