FR 6926 then FR 133 at Barcelona
Rome → Barcelona → Berlin
Timetable, Barcelona time
20:20FR 6926 from Rome at the gate
16:55FR 133 to Berlin leaves the gate
20 h 35 apart on the timetable, overnight
FR 133 leaves 20 h 35 after FR 6926 arrives on the timetable: more than half a day, so not a connection we count.