FR 7542 then EC 7173 at Barcelona
Manchester → Barcelona → Berlin
Timetable, Barcelona time
10:15FR 7542 from Manchester at the gate
07:20EC 7173 to Berlin leaves the gate
21 h 05 apart on the timetable, overnight
EC 7173 leaves 21 h 05 after FR 7542 arrives on the timetable: more than half a day, so not a connection we count.