FR 775 then EW 9445 at Barcelona
Torino → Barcelona → Düsseldorf
Timetable, Barcelona time
17:30FR 775 from Torino at the gate
16:20EW 9445 to Düsseldorf leaves the gate
22 h 50 apart on the timetable, overnight
EW 9445 leaves 22 h 50 after FR 775 arrives on the timetable: more than half a day, so not a connection we count.