FR 775 then LL 5026 at Barcelona
Torino → Barcelona → Brussels
Timetable, Barcelona time
20:00FR 775 from Torino at the gate
19:00LL 5026 to Brussels leaves the gate
23 h apart on the timetable, overnight
LL 5026 leaves 23 h after FR 775 arrives on the timetable: more than half a day, so not a connection we count.