FR 775 then QR 3636 at Barcelona
Torino → Barcelona → Firenze
Timetable, Barcelona time
09:20FR 775 from Torino at the gate
21:30QR 3636 to Firenze leaves the gate
12 h 10 apart on the timetable
QR 3636 leaves 12 h 10 after FR 775 arrives on the timetable: more than half a day, so not a connection we count.