FR 776 then LL 5130 at Barcelona
Venezia → Barcelona → Alicante
Timetable, Barcelona time
15:35FR 776 from Venezia at the gate
12:40LL 5130 to Alicante leaves the gate
21 h 05 apart on the timetable, overnight
LL 5130 leaves 21 h 05 after FR 776 arrives on the timetable: more than half a day, so not a connection we count.