FR 776 then VY 1220 at Barcelona
Venezia → Barcelona → Valladolid
Timetable, Barcelona time
23:30FR 776 from Venezia at the gate
16:05VY 1220 to Valladolid leaves the gatealso IB 5472
16 h 35 apart on the timetable, overnight
VY 1220 leaves 16 h 35 after FR 776 arrives on the timetable: more than half a day, so not a connection we count.