FR 776 then W4 6316 at Barcelona
Venezia → Barcelona → Milan
Timetable, Barcelona time
23:30FR 776 from Venezia at the gate
13:10W4 6316 to Milan leaves the gate
13 h 40 apart on the timetable, overnight
W4 6316 leaves 13 h 40 after FR 776 arrives on the timetable: more than half a day, so not a connection we count.