FR 7807 then FR 133 at Barcelona
London Luton → Barcelona → Berlin
Timetable, Barcelona time
17:45FR 7807 from London Luton at the gate
16:55FR 133 to Berlin leaves the gate
23 h 10 apart on the timetable, overnight
FR 133 leaves 23 h 10 after FR 7807 arrives on the timetable: more than half a day, so not a connection we count.