FR 8214 then IB 5096 at Barcelona
London Stansted → Barcelona → Porto
Timetable, Barcelona time
22:20FR 8214 from London Stansted at the gate
20:25IB 5096 to Porto leaves the gate
22 h 05 apart on the timetable, overnight
IB 5096 leaves 22 h 05 after FR 8214 arrives on the timetable: more than half a day, so not a connection we count.