FR 8214 then W4 6020 at Barcelona
London Stansted → Barcelona → Rome
Timetable, Barcelona time
22:20FR 8214 from London Stansted at the gate
22:00W4 6020 to Rome leaves the gate
23 h 40 apart on the timetable, overnight
W4 6020 leaves 23 h 40 after FR 8214 arrives on the timetable: more than half a day, so not a connection we count.