FR 8216 then EC 7155 at Barcelona
London Stansted → Barcelona → Milan
Timetable, Barcelona time
20:35FR 8216 from London Stansted at the gate
18:50EC 7155 to Milan leaves the gate
22 h 15 apart on the timetable, overnight
EC 7155 leaves 22 h 15 after FR 8216 arrives on the timetable: more than half a day, so not a connection we count.