FR 8216 then FR 133 at Barcelona
London Stansted → Barcelona → Berlin
Timetable, Barcelona time
23:55FR 8216 from London Stansted at the gate
16:55FR 133 to Berlin leaves the gate
17 h apart on the timetable, overnight
FR 133 leaves 17 h after FR 8216 arrives on the timetable: more than half a day, so not a connection we count.