FR 879 then FR 133 at Barcelona
Venezia → Barcelona → Berlin
Timetable, Barcelona time
22:30FR 879 from Venezia at the gate
16:55FR 133 to Berlin leaves the gate
18 h 25 apart on the timetable, overnight
FR 133 leaves 18 h 25 after FR 879 arrives on the timetable: more than half a day, so not a connection we count.