FR 879 then FR 149 at Barcelona
Venezia → Barcelona → Berlin
Timetable, Barcelona time
22:30FR 879 from Venezia at the gate
14:20FR 149 to Berlin leaves the gate
15 h 50 apart on the timetable, overnight
FR 149 leaves 15 h 50 after FR 879 arrives on the timetable: more than half a day, so not a connection we count.