HV 5133 then FR 4545 at Barcelona
Amsterdam → Barcelona → Porto
Timetable, Barcelona time
20:05HV 5133 from Amsterdam at the gate
17:15FR 4545 to Porto leaves the gate
21 h 10 apart on the timetable, overnight
FR 4545 leaves 21 h 10 after HV 5133 arrives on the timetable: more than half a day, so not a connection we count.