IB 2471 then FR 133 at Barcelona
Leon → Barcelona → Berlin
Timetable, Barcelona time
12:35IB 2471 from Leon at the gatealso LL 3101, VY 5871, QR 6959
11:50FR 133 to Berlin leaves the gate
23 h 15 apart on the timetable, overnight
FR 133 leaves 23 h 15 after IB 2471 arrives on the timetable: more than half a day, so not a connection we count.