IB 5093 then FR 133 at Barcelona
Porto → Barcelona → Berlin
Timetable, Barcelona time
17:20IB 5093 from Porto at the gate
11:50FR 133 to Berlin leaves the gate
18 h 30 apart on the timetable, overnight
FR 133 leaves 18 h 30 after IB 5093 arrives on the timetable: more than half a day, so not a connection we count.