IB 5093 then FR 149 at Barcelona
Porto → Barcelona → Berlin
Timetable, Barcelona time
17:20IB 5093 from Porto at the gate
14:20FR 149 to Berlin leaves the gate
21 h apart on the timetable, overnight
FR 149 leaves 21 h after IB 5093 arrives on the timetable: more than half a day, so not a connection we count.