IB 5093 then FR 6559 at Barcelona
Porto → Barcelona → Liverpool
Timetable, Barcelona time
17:20IB 5093 from Porto at the gate
12:50FR 6559 to Liverpool leaves the gate
19 h 30 apart on the timetable, overnight
FR 6559 leaves 19 h 30 after IB 5093 arrives on the timetable: more than half a day, so not a connection we count.