IB 5135 then FR 133 at Barcelona
Alicante → Barcelona → Berlin
Timetable, Barcelona time
15:50IB 5135 from Alicante at the gate
11:50FR 133 to Berlin leaves the gate
20 h apart on the timetable, overnight
FR 133 leaves 20 h after IB 5135 arrives on the timetable: more than half a day, so not a connection we count.