IB 5145 then FR 2507 at Barcelona
Seville → Barcelona → Cologne
Timetable, Barcelona time
10:35IB 5145 from Seville at the gate
06:20FR 2507 to Cologne leaves the gate
19 h 45 apart on the timetable, overnight
FR 2507 leaves 19 h 45 after IB 5145 arrives on the timetable: more than half a day, so not a connection we count.