IB 5341 then FR 133 at Barcelona
Rome → Barcelona → Berlin
Timetable, Barcelona time
17:05IB 5341 from Rome at the gatealso LL 5341
16:55FR 133 to Berlin leaves the gate
23 h 50 apart on the timetable, overnight
FR 133 leaves 23 h 50 after IB 5341 arrives on the timetable: more than half a day, so not a connection we count.