IB 5355 then FR 149 at Barcelona
Milan → Barcelona → Berlin
Timetable, Barcelona time
14:55IB 5355 from Milan at the gatealso LL 5355, VY 6043
14:20FR 149 to Berlin leaves the gate
23 h 25 apart on the timetable, overnight
FR 149 leaves 23 h 25 after IB 5355 arrives on the timetable: more than half a day, so not a connection we count.